Sergio Ayala, Jr., Zhenjie Zhang and Seth M. Cohen
Chem. Commun., 2017,53, 3058-3061
DOI:
10.1039/C6CC10225E,
Communication
The first polymer–MOF hybrid material (polyMOF) with a UiO-66 architecture is reported, prepared from polymers with varying alkyl spacers, molecular weights, and dispersities. With appropriate spacing, mesoporous UiO-66 polyMOF can be obtained having an uncommon, interlaced crystal morphology, suggesting that polyMOFs can be used to generate MOF materials with hierarchical architectures.
