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A nitro-substituted dipyrrolylphenol was synthesized as a precursor of a π-electronic anion, whose phenolate (phenoxide) moiety upon deprotonation was stabilized by the hydrogen-bond-donating pyrrole NH, thus forming solid-state ion pairs with various cationic species.

Graphical abstract: Dipyrrolyphenol as a precursor of π-electronic anion that forms ion pairs with cations

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