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Upon switching the counter-ion to a highly lipophilic anion, a series of phosphorescent cationic organoplatinum(II) salts are rendered soluble in non-polar solvents and can further self-organize into lamellar nanostructures, breath-figure arrays and smectic mesophases.

Graphical abstract: Phosphorescent organoplatinum(ii) complexes with a lipophilic anion: supramolecular soft nanomaterials through ionic self-assembly and metallophilicity

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