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A hyperbranched supramolecular polymer has been constructed through orthogonal self-crosslinking by two classical binding interactions: triple hydrogen bonding interaction between a three-arm melamine derivative and DB24C8-containing bisimide and host–guest interaction between DB24C8 crown ether and ditopic dibenzyl ammonium moieties.

Graphical abstract: A hyperbranched supramolecular polymer constructed by orthogonal triple hydrogen bonding and host–guest interactions

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