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Abstract | Cited by

We report the synthesis, crystal structure and exfoliation of a new member of an important family of layered compounds: lamellar pyrimidinethiolate coordination polymers. Conductivity measurements and DFT calculations of iron(II) pyrimidine-2-thiolate show that this material and a related compound are insulators.

Graphical abstract: Layered structures and nanosheets of pyrimidinethiolate coordination polymers

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