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Complexes [MnMST(NH3)]n−3 (Mn = FeII, FeIII, GaIII) were prepared and each contains an intramolecular hydrogen bonding network involving the ammonia ligand. Deprotonation of the FeIII–NH3 complex afforded a putative [FeIIIMST(NH2)] species whose reactivity has been explored.

Graphical abstract: Synthesis, structure and reactivity of FeII/III–NH3 complexes bearing a tripodal sulfonamido ligand

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