Nathaniel S. Sickerman, Sonja M. Peterson, Joseph W. Ziller and A. S. Borovik
Chem. Commun., 2014,50, 2515-2517
DOI:
10.1039/C3CC48804G,
Communication
Complexes [MnMST(NH3)]n−3 (Mn = FeII, FeIII, GaIII) were prepared and each contains an intramolecular hydrogen bonding network involving the ammonia ligand. Deprotonation of the FeIII–NH3 complex afforded a putative [FeIIIMST(NH2)]− species whose reactivity has been explored.