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Novel mono- and dimolybdenum–dinitrogen complexes bearing an arsenic-containing ANA-type pincer ligand are prepared and characterized by X-ray analyses. These complexes afford a stoichiometric amount of ammonia by treatment with sulfuric acid at room temperature.

Graphical abstract: Preparation and reactivity of molybdenum–dinitrogen complexes bearing an arsenic-containing ANA-type pincer ligand

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