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Abstract | Cited by

Zr and Hf based MOFs with enhanced pore accessibility for large molecules and good hydrothermal stability were obtained using a bent dithienothiophene dicarboxylate and Zr4+ or Hf4+ source. A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology.

Graphical abstract: Zr(iv) and Hf(iv) based metal–organic frameworks with reo-topology

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