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Novel gold(I) “click” carbene(1,2,3-triazolylidene) complexes have been synthesised, characterised and exploited for the self-assembly of a metallomacrocycle and as precatalysts for gold(I)-catalysed reactions.

Graphical abstract: Gold(i) “click” 1,2,3-triazolylidenes: synthesis, self-assembly and catalysis

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