Issue 11, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

Catalytic conversions in water: 17O, {1H}31P and 35Cl NMR study of a novel stoichiometric redox reaction between PdCl2, tppts and H2O [tppts = P(C6H4-m-SO3Na)3]

Georgios Papadogianakis,   Joop A. Peters,   Leendert Maat  and  Roger A. Sheldon  

Abstract

17 O, {1H}31P and 35Cl NMR are used to investigate the mechanism of the reaction of PdCl2 with tppts [tppts = P(C6H4-m-SO3Na)3] in 17O enriched water to give the novel complex [PdCl(tppts)3]+1, which is reduced quantitatively to Pd(tppts)32 with tppts (8 d, 25 °C); with CO (2 bar) reduction to 2 is quantitative in 5 min at 25 °C.

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Article information

DOI
https://doi.org/10.1039/C39950001105
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1105-1106

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Catalytic conversions in water: 17O, {1H}31P and 35Cl NMR study of a novel stoichiometric redox reaction between PdCl2, tppts and H2O [tppts = P(C6H4-m-SO3Na)3]

G. Papadogianakis, J. A. Peters, L. Maat and R. A. Sheldon, J. Chem. Soc., Chem. Commun., 1995, 1105 DOI: 10.1039/C39950001105

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