Perfluoro-cis-2,3-dialkyloxaziridines 1 perform the direct epoxidation of glycals 2 to give cleanly corresponding 1,2-anhydrosugars 3 with medium to complete diastereoselection; elaboration of these glycals to glycosyl fluorides and lipid conjugates is also reported.
M. Cavicchioli, A. Mele, V. Montanari and G. Resnati, J. Chem. Soc., Chem. Commun., 1995, 901 DOI: 10.1039/C39950000901
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