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Abstract | Cited by

The first vinyl-linked PPh3-based covalent-organic frameworks (Pd@TMBen-PPh3 and Pd@TMBen-4F-PPh3) were facilely constructed via direct three-component Knoevenagel condensation, which could serve as outstanding heterogeneous catalysts for the Pd-catalyzed carbonylation coupling reaction owing to the synergistic effect of the flexible PPh3-ligated Pd complexes and the rigid framework.

Graphical abstract: Robust phosphine-based covalent-organic framework palladium catalysts for the highly efficient carbonylation coupling reaction

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