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Abstract | Cited by

A new molecularly imprinted Ru–porphyrin complex catalyst on a SiO2 support was designed, prepared, and characterized in a step-by-step manner for the C5[double bond, length as m-dash]C6 epoxidation of cholesterol derivatives. High chemoselectivity for the C5[double bond, length as m-dash]C6 epoxidation of cholesterol derivatives without protecting the 3-position OH group and other oxidizable functional groups was achieved on the molecularly imprinted catalyst.

Graphical abstract: Chemoselective epoxidation of cholesterol derivatives on a surface-designed molecularly imprinted Ru–porphyrin catalyst

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