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Abstract | Cited by

The novel bimetallic bis(pentalene) complex Ti2(μ:η5,η5-Pn†)2 (Pn† = C8H4{SiiPr3-1,4}2) has been synthesised and structurally characterised. Structural data show a Ti–Ti distance of 2.399(2) Å, consistent with a strong metal–metal interaction, which DFT calculations best describe as a double bond with σ and π components.

Graphical abstract: Bis(pentalene)di-titanium: a bent double-sandwich complex with a very short Ti–Ti bond

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