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Abstract | Cited by

The enantioselective intramolecular alkylation of substituted imidazoles with enantiomeric excesses up to 98% has been accomplished by rhodium catalyzed C–H bond functionalization with (S,S′,R,R′)TangPhos as the chiral ligand.

Graphical abstract: Rhodium catalyzed enantioselective cyclization of substituted imidazoles via C–H bond activation

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