Issue 19, 1995

New polynuclear nickel complexes with a variety of pyridonate and carboxylate ligands

Abstract

A general synthetic strategy for making, and structures and some properties of, several new polynuclear nickel complexes of pyridonate ligands are reported: these complexes include a linear trinuclear complex [Ni3(ChP)4(O2CMe)2(MeOH)6], a tetranuclear cubane [Ni4(OMe)4(η-ChP)(ChP)3(MeOH)7] and two undecanuclear complexes [Ni11(µ-OH)6(O2CMe)6(mhp)9(H2O)3]2[CO3] and [Ni113-OH)6(O2CMe)7(mhp)9(Hmhp)2](Hchp and Hmhp = 6-chloro- and 6-methyl-2-pyridone respectively).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1983-1985

New polynuclear nickel complexes with a variety of pyridonate and carboxylate ligands

A. J. Blake, E. K. Brechin, A. Codron, R. O. Gould, C. M. Grant, S. Parsons, J. M. Rawson and R. E. P. Winpenny, J. Chem. Soc., Chem. Commun., 1995, 1983 DOI: 10.1039/C39950001983

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