The unnatural enantiomer of anatoxin-a is prepared in enantiomerically pure form by a concise route involving enantioselective enolisation of a tropinone derivative by a chiral lithium amide base as the key step.
N. J. Newcombe and N. S. Simpkins, J. Chem. Soc., Chem. Commun., 1995, 831 DOI: 10.1039/C39950000831
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