Issue 4, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

Formation of a chelating bidentate nitrosoalkane complex of ruthenium(II) through reaction of H2O with a high-valent bis(imido)ruthenium intermediate and X-ray crystal structure of [Ru(bpy)2(ONCMe2CMe2NO)][ClO4]2·Me2CO

Wing-Hong Chiu,   Kung-Kai Cheung  and  Chi-Ming Che  

Abstract

Oxidation of [RuII(bpy)2(NH2CMe2CMe2NH2)]2+ by CeIV in H2O generates the highly reactive cis-bis(imido)ruthenium(VI) intermediate, which reacts with H2O to give [RuII(bpy)2(ONCMe2CMe2NO)]2+, the structure of which has been determined by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/C39950000441
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 441-442

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Formation of a chelating bidentate nitrosoalkane complex of ruthenium(II) through reaction of H2O with a high-valent bis(imido)ruthenium intermediate and X-ray crystal structure of [Ru(bpy)2(ONCMe2CMe2NO)][ClO4]2·Me2CO

W. Chiu, K. Cheung and C. Che, J. Chem. Soc., Chem. Commun., 1995, 441 DOI: 10.1039/C39950000441

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