Issue 5, 2022

Methyltrioxorhenium (MTO) catalysis in the epoxidation of alkenes: a synthetic overview

Abstract

Epoxidation of alkenes is one of the most explored reactions in organic synthesis because of the accessibilities of diverse important compounds from epoxides. Several transition-metal catalysts, in combination with oxidizing agents, have been successfully utilized to achieve alkene epoxides. In this context, methyltrioxorhenium (MTO)-catalyzed epoxidation of alkenes in accordance with different oxidants has been widely reconnoitred where the Lewis acidity of rhenium (Re) is diminished by different Lewis bases to suppress the decomposition of epoxides to diols. Although great success has been accomplished, no review article on MTO-catalyzed epoxidation has been published to date. Therefore, all the advancements in methyltrioxorhenium (MTO)-catalyzed epoxidation of alkenes using different oxidizing agents (aq. H2O2, urea-H2O2, and sodium percarbonate) have been summarized in this comprehensive review article for the scientific community.

Graphical abstract: Methyltrioxorhenium (MTO) catalysis in the epoxidation of alkenes: a synthetic overview

Article information

Article type
Perspective
Submitted
17 Қаз. 2021
Accepted
21 Жел. 2021
First published
21 Жел. 2021

New J. Chem., 2022,46, 2005-2027

Methyltrioxorhenium (MTO) catalysis in the epoxidation of alkenes: a synthetic overview

S. Verma, A. Joshi, S. R. De and J. L. Jat, New J. Chem., 2022, 46, 2005 DOI: 10.1039/D1NJ04950J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements