Issue 54, 2021

Fusing pyrene and ferrocene into a chiral, redox-active triangle

Abstract

A macrocycle that integrates three ferrocene–pyrene dyads in a triangular C2-symmetric arrangement is synthesised as a racemate in a simple one-pot approach. Crystal structural analysis reveals two enantiomeric conformers that pack alternatingly via π–π stacking and interconvert dynamically in solution. Electrochemical investigations indicate weak electrostatic interactions between Fc groups upon oxidation to a mixed valence triangle.

Graphical abstract: Fusing pyrene and ferrocene into a chiral, redox-active triangle

Supplementary files

Article information

Article type
Communication
Submitted
25 Сәу. 2021
Accepted
07 Мау. 2021
First published
07 Мау. 2021

Chem. Commun., 2021,57, 6660-6663

Fusing pyrene and ferrocene into a chiral, redox-active triangle

M. Metzelaars, S. Sanz, J. Rawson, R. Hartmann, C. M. Schneider and P. Kögerler, Chem. Commun., 2021, 57, 6660 DOI: 10.1039/D1CC02191E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements