Issue 45, 2020

Silicon incorporation in polymethine dyes

Abstract

Methods to red-shift fluorophores have garnered considerable interest due to the broad utility of low energy light. The incorporation of silicon into xanthene and coumarin scaffolds has resulted in an array of visible and near-infrared fluorophores. Here, we extend this approach to polymethine dyes, another popular fluorophore class, performing experimental and computational analyses. We found that when oxygen was replaced with SiMe2, bathochromic shifts of up to 121 nm and fluorophores with emission above 900 nm were achieved.

Graphical abstract: Silicon incorporation in polymethine dyes

Supplementary files

Article information

Article type
Communication
Submitted
12 Жел. 2019
Accepted
02 Сәу. 2020
First published
01 Мам. 2020

Chem. Commun., 2020,56, 6110-6113

Author version available

Silicon incorporation in polymethine dyes

M. Pengshung, P. Neal, T. L. Atallah, J. Kwon, J. R. Caram, S. A. Lopez and E. M. Sletten, Chem. Commun., 2020, 56, 6110 DOI: 10.1039/C9CC09671J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements