Issue 38, 2009
From the journal:

Chemical Communications

Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters†‡

Ahmad Masarwa,a   Alois Fürstnerb  and  Ilan Marek*a  

* Corresponding authors

a The Mallat Family Laboratory of Organic Chemistry, Schulich Faculty of Chemistry and the Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa 32000, Israel
E-mail: chilanm@tx.technion.ac.il
Fax: +972 4 829 3709

b Max-Planck-Institute fur Kohlenforschung, D-45470 Mülheim/Ruhr, Germany

Abstract

Pd(II)- and Pt(II)-catalyzed ring-expansion of enantiomerically pure alkylidenecyclopropane derivatives leads to the formation of cyclobutene species with a complete preservation of the stereogenic center.

Graphical abstract: Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B910465H
Article type
Communication
Submitted
28 Мам. 2009
Accepted
07 Там. 2009
First published
02 Қыр. 2009

Chem. Commun., 2009, 5760-5762

Permissions

Request permissions

Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

A. Masarwa, A. Fürstner and I. Marek, Chem. Commun., 2009, 5760 DOI: 10.1039/B910465H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements