Issue 3, 2006

Solvent-free synthesis of a microporous metal–organic framework

Abstract

We describe the first solvent-free mechanochemical synthesis of a microporous metal–organic framework [Cu(INA)2] (INA = isonicotinic acid); the product has robust 3-dimensional connectivity and is obtained quantitatively by grinding together copper acetate and isonicotinic acid for 10 minutes without any applied heating—the high efficiency of the synthesis suggests that mechanochemical synthesis should be further investigated as a convenient method for the preparation of microporous metal–organic frameworks (MOFs).

Graphical abstract: Solvent-free synthesis of a microporous metal–organic framework

Supplementary files

Article information

Article type
Communication
Submitted
28 Қыр. 2005
Accepted
25 Қаң. 2006
First published
06 Ақп. 2006

CrystEngComm, 2006,8, 211-214

Solvent-free synthesis of a microporous metal–organic framework

A. Pichon, A. Lazuen-Garay and S. L. James, CrystEngComm, 2006, 8, 211 DOI: 10.1039/B513750K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements