Issue 78, 2024

Streamlining Si–O bond formation through cobalt-catalyzed dehydrocoupling

Abstract

Herein we report a strategy for the synthesis of organosilicons, including siloxanes, silyl ethers, and aminosilanes, via Co-catalyzed dehydrogenative coupling between hydrosilanes and nucleophiles. This discovery represents an expansion of the synthetic toolkit for organosilicon synthesis, forging Si–O and Si–N bonds in the presence of cobalt complexes with salen-type ligands.

Graphical abstract: Streamlining Si–O bond formation through cobalt-catalyzed dehydrocoupling

Supplementary files

Article information

Article type
Communication
Submitted
16 Там. 2024
Accepted
04 Қыр. 2024
First published
05 Қыр. 2024

Chem. Commun., 2024,60, 10886-10889

Streamlining Si–O bond formation through cobalt-catalyzed dehydrocoupling

E. Szafoni, D. Lewandowski, M. Gruszczyński, K. Broniarz, H. Stachowiak-Dłużyńska, K. Kuciński and G. Hreczycho, Chem. Commun., 2024, 60, 10886 DOI: 10.1039/D4CC04144E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements