Ligand effects on gas adsorption in nanoporous phthalocyanine crystals†
Abstract
X-ray diffraction is used to study the sorption of CO and NO in two phthalocyanine nanoporous crystals (PNCs) with 4,4′ bipyridine or 4,4′ bipyrimidine trans coordinated to open Co2+ sites, demonstrating how the trans coordinated ligands influence the gas sorption properties and structures of the PNCs.
- This article is part of the themed collections: Chemical Communications HOT Articles 2024 and ChemComm 60th Anniversary Collection