Progress in the chemistry of molecular actinide-nitride compounds

Abstract

The chemistry of actinide-nitrides has witnessed significant advances in the last ten years with a large focus on uranium and a few breakthroughs with thorium. Following the early discovery of the first terminal and bridging nitride complexes, various synthetic routes to uranium nitrides have since been identified, although the range of ligands capable of stabilizing uranium nitrides still remains scarce. In particular, both terminal- and bridging-nitrides possess attractive advantages for potential reactivity, especially in light of the recent development of uranium complexes for dinitrogen reduction and functionalization. The first molecular thorium bridged-nitride complexes have also been recently identified, anticipating the possibility of expanding nitride chemistry not only to low-valent thorium, but also to the transuranic elements.