Issue 19, 2023

Visible-light-promoted C(sp3)–H thiolation of aliphatic ethers with thiosulfonates

Abstract

A visible-light-promoted direct thiolation of α-C(sp3)–H in ethers with thiosulfonates was developed for the preparation of α-arylthioethers using easily availably Na2-eosin Y and TBHP as a photocatalyst and oxidant. This reaction occurred smoothly under the irradiation of 5 W blue light at room temperature and generated the corresponding products in good to excellent yields.

Graphical abstract: Visible-light-promoted C(sp3)–H thiolation of aliphatic ethers with thiosulfonates

Supplementary files

Article information

Article type
Communication
Submitted
03 Нау. 2023
Accepted
24 Сәу. 2023
First published
24 Сәу. 2023

New J. Chem., 2023,47, 9035-9039

Visible-light-promoted C(sp3)–H thiolation of aliphatic ethers with thiosulfonates

W. Bi, Q. Liu, C. Li, W. Zhang, S. Feng, Y. Geng, X. Chen and L. Qu, New J. Chem., 2023, 47, 9035 DOI: 10.1039/D3NJ01029E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements