A {Na2Fe10} isobutyrate cluster, interlinked into 1D chains

Daniel Podgornii; Jan van Leusen; Victor Ch. Kravtsov; Paul Kögerler; Svetlana G. Baca

doi:10.1039/D1CE00777G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A {Na₂Fe₁₀} isobutyrate cluster, interlinked into 1D chains†

Daniel Podgornii,^a Jan van Leusen,

^b Victor Ch. Kravtsov,

^a Paul Kögerler

*^b and Svetlana G. Baca

*^a

Author affiliations

* Corresponding authors

^a Institute of Applied Physics, Academiei 5, 2028 Chisinau, Republic of Moldova
E-mail: sbaca_md@yahoo.com

^b Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany
E-mail: paul.koegerler@ac.rwth-aachen.de

Abstract

Charge-neutral [Na₂Fe₁₀O₆(OH)₄(isobutyrate)₁₄(MeO)₂(MeCN)₂] coordination clusters, comprising a hollow ‘Chinese lantern’-like shell of six condensed planar triangular {Fe^III₃(μ₃-O)} motifs, form upon ultrasonication of trinuclear Fe(III) isobutyrate units in acetonitrile in the presence of sodium azide and 4,4′-bipyridine (bpy), resulting in {[Na₂Fe₁₀O₆(OH)₄(isobutyrate)₁₄(bpy)(MeO)₂(MeCN)₂]·MeOH}_n in which the dodecanuclear cluster units are bpy-bridged into 1D chains.

This article is part of the themed collection: Coordination Networks

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D1CE00777G
Article type: Communication
Submitted: 10 Мау. 2021
Accepted: 19 Шіл. 2021
First published: 20 Шіл. 2021

Download Citation

CrystEngComm, 2021,23, 5153-5156

Permissions

Request permissions

A {Na₂Fe₁₀} isobutyrate cluster, interlinked into 1D chains

D. Podgornii, J. van Leusen, V. Ch. Kravtsov, P. Kögerler and S. G. Baca, CrystEngComm, 2021, 23, 5153 DOI: 10.1039/D1CE00777G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

CrystEngComm