Slow relaxation of the magnetization, reversible solvent exchange and luminescence in 2D anilato-based frameworks†‡
Samia
Benmansour, 
*a
Antonio
Hernández-Paredes,
a
Arpan
Mondal,
b
Josep
Canet-Ferrer,
a
Sanjit
Konar
b
and
Carlos J.
Gómez-García
*a
*a
Antonio
Hernández-Paredes,
a
Arpan
Mondal,
b
Josep
Canet-Ferrer,
a
Sanjit
Konar
b
and
Carlos J.
Gómez-García
*a
Abstract
A series of multifunctional 2D frameworks prepared with Dy(III) and the bromanilato ligand, formulated as: [Dy2(C6O4Br2)3(G)n]·nG with G = H2O, dimethylformamide (dmf) and dimethylsulfoxide (dmso), can exchange the coordinated and non-coordinated solvent molecules (G) in a reversible way. These multifunctional frameworks show field induced slow relaxation of the magnetization and luminescence that can be easily and reversibly modified by solvent exchange.
- This article is part of the themed collection: Functional Coordination Networks
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