Issue 17, 2019

Cyclopropane–alkene metathesis by gold(i)-catalyzed decarbenation of persistent cyclopropanes

Abstract

A gold(I)-catalyzed cyclopropane–alkene metathesis has been demonstrated with two new families of cyclopropane derivatives of naphthalene and phenanthrene (benzo-fused norcaradienes). In this process, metal carbene units are transferred from a persistent cyclopropane to an alkene, upon release of naphthalene or phenanthrene, allowing the diastereoselective synthesis of a wide range of aryl and vinyl cyclopropanes.

Graphical abstract: Cyclopropane–alkene metathesis by gold(i)-catalyzed decarbenation of persistent cyclopropanes

Supplementary files

Article information

Article type
Communication
Submitted
13 Ақп. 2019
Accepted
23 Нау. 2019
First published
27 Нау. 2019

Org. Biomol. Chem., 2019,17, 4216-4219

Cyclopropane–alkene metathesis by gold(I)-catalyzed decarbenation of persistent cyclopropanes

M. Mato, I. Martín-Torres, B. Herlé and A. M. Echavarren, Org. Biomol. Chem., 2019, 17, 4216 DOI: 10.1039/C9OB00359B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements