Issue 14, 2019

Beyond quantum confinement: excitonic nonlocality in halide perovskite nanoparticles with Mie resonances

Abstract

Halide perovskite nanoparticles have demonstrated pronounced quantum confinement properties for nanometer-scale sizes and strong Mie resonances for 102 nm sizes. Here we studied the intermediate sizes where the nonlocal response of the exciton affects the spectral properties of Mie modes. The mechanism of this effect is associated with the fact that excitons in nanoparticles have an additional kinetic energy that is proportional to k2, where k is the wavenumber. Therefore, they possess higher energy than in the case of static excitons. The obtained experimental and theoretical results for MAPbBr3 nanoparticles of various sizes (2–200 nm) show that for particle radii comparable with the Bohr radius of the exciton (a few nanometers in perovskites), the blue-shift of the photoluminescence, scattering, and absorption cross-section peaks related to quantum confinement should be dominating due to the weakness of Mie resonances for such small sizes. On the other hand, for larger sizes (more than 50–100 nm), the influence of Mie modes increases, and the blue shift remains despite the fact that the effect of quantum confinement becomes much weaker.

Graphical abstract: Beyond quantum confinement: excitonic nonlocality in halide perovskite nanoparticles with Mie resonances

Supplementary files

Article information

Article type
Paper
Submitted
05 Жел. 2018
Accepted
11 Нау. 2019
First published
11 Нау. 2019

Nanoscale, 2019,11, 6747-6754

Beyond quantum confinement: excitonic nonlocality in halide perovskite nanoparticles with Mie resonances

A. S. Berestennikov, Y. Li, I. V. Iorsh, A. A. Zakhidov, A. L. Rogach and S. V. Makarov, Nanoscale, 2019, 11, 6747 DOI: 10.1039/C8NR09837A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements