Volume 214, 2019

Assistance of metal nanoparticles in photocatalysis – nothing more than a classical heat source

Abstract

In a recent paper, we derived a self-consistent theory of the steady-state electron distribution of a metal under continuous wave illumination which treats thermal and non-thermal effects on the same footing. Here, we re-derive the main analytical results of that study from very simple arguments, and draw a series of conclusions which contradict claims made in previous studies of the steady-state distribution. In particular, we show that the faster chemical reactions reported in many previous papers are extremely unlikely to originate from high energy non-thermal electrons. Instead, the faster reactions very likely originate from a purely thermal effect.

Graphical abstract: Assistance of metal nanoparticles in photocatalysis – nothing more than a classical heat source

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Article information

Article type
Paper
Submitted
04 Қаз. 2018
Accepted
02 Қар. 2018
First published
02 Қар. 2018

Faraday Discuss., 2019,214, 215-233

Assistance of metal nanoparticles in photocatalysis – nothing more than a classical heat source

Y. Sivan, I. W. Un and Y. Dubi, Faraday Discuss., 2019, 214, 215 DOI: 10.1039/C8FD00147B

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