Issue 31, 2018

Post-functionalization of a photoactive hybrid polyoxotungstate

Abstract

A new post-functionalization strategy for hybrid polyoxometalate (POM) clusters is presented, whereby the electronic properties and visible-light driven oxidative reactivity of the POM core can be altered by controlled addition of transition metal ions. The structure of three new metal-functionalised derivatives of a phosphonate hybrid-POM are discussed, alongside a comparison of their electrochemical, photo-chemical and photo-oxidative properties.

Graphical abstract: Post-functionalization of a photoactive hybrid polyoxotungstate

Supplementary files

Article information

Article type
Paper
Submitted
30 Нау. 2018
Accepted
09 Мам. 2018
First published
15 Мам. 2018

Dalton Trans., 2018,47, 10590-10594

Post-functionalization of a photoactive hybrid polyoxotungstate

J. M. Cameron, S. Fujimoto, R. Wei, G. N. Newton and H. Oshio, Dalton Trans., 2018, 47, 10590 DOI: 10.1039/C8DT01253A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements