In this work the synthesis of a geometrically constrained phosphenium cation is shown. In contrast to previously reported phosphenium cations, the geometrical constriction of the P-center in this cation makes it ambiphilic and reactive towards small molecules such as H2O, ROH and NH3.
S. Volodarsky and R. Dobrovetsky, Chem. Commun., 2018, 54, 6931 DOI: 10.1039/C8CC02423E
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