Issue 16, 2018

Arrested disproportionation in trivalent, mononuclear, and non-metallocene complexes of Zr(iii) and Hf(iii)

Abstract

Reduction of the group 4 transition metal precursors [(PN)2MCl2] (M = Zr (1), and Hf (2)); PN = (N-(2-(diisopropylphosphino)-4-methylphenyl)-2,4,6-trimethylanilide), both readily prepared by transmetallation of 2 LiPN with [MCl4(THF)2], with a slight excess of KC8, resulted in the isolation of the trivalent complexes [(PN)2MCl] (M = Zr (3), and Hf (4)). Complexes 1–4 were all identified by solid-state X-ray diffraction analysis, whereas in the case of 3 and 4 low temperature X-band EPR spectroscopy allowed for the identification of these metal-centered d1 radicals. A comparison with the isostructural and isoelectronic but more stable [(PN)2TiCl] is also presented.

Graphical abstract: Arrested disproportionation in trivalent, mononuclear, and non-metallocene complexes of Zr(iii) and Hf(iii)

Supplementary files

Article information

Article type
Communication
Submitted
16 Қар. 2017
Accepted
26 Қаң. 2018
First published
26 Қаң. 2018

Chem. Commun., 2018,54, 2052-2055

Arrested disproportionation in trivalent, mononuclear, and non-metallocene complexes of Zr(III) and Hf(III)

L. N. Grant, M. E. Miehlich, K. Meyer and D. J. Mindiola, Chem. Commun., 2018, 54, 2052 DOI: 10.1039/C7CC08815A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements