Issue 38, 2009
From the journal:

Chemical Communications

Getting the sterics just right: a five-coordinate iridium trisboryl complex that reacts with C–H bonds at room temperature†

Ghayoor A. Chotana,a   Britt A. Vanchura, II,a   Man Kin Tse,a   Richard J. Staples,a   Robert E. Maleczka, Jr*a  and  Milton R. Smith, III*a  

* Corresponding authors

a Department of Chemistry, Michigan State University, East Lansing, MI 48824-1322, USA
E-mail: smithmil@msu.edu, maleczka@chemistry.msu.edu
Fax: +1 517-353-1793
Tel: +1 517-355-9715 x166/x124

Abstract

Five-coordinate boryl complexes relevant to Ir mediated C–H borylations have been synthesized, providing a glimpse of the most fundamental step in the catalytic cycle for the first time.

Graphical abstract: Getting the sterics just right: a five-coordinate iridium trisboryl complex that reacts with C–H bonds at room temperature

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Article information

DOI
https://doi.org/10.1039/B914736E
Article type
Communication
Submitted
21 Шіл. 2009
Accepted
17 Там. 2009
First published
04 Қыр. 2009

Chem. Commun., 2009, 5731-5733

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Getting the sterics just right: a five-coordinate iridium trisboryl complex that reacts with C–H bonds at room temperature

G. A. Chotana, B. A. Vanchura, II, M. K. Tse, R. J. Staples, R. E. Maleczka, Jr and M. R. Smith, III, Chem. Commun., 2009, 5731 DOI: 10.1039/B914736E

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