Issue 22, 2021

Supramolecular assembly of a hierarchically structured 3D potassium vanadate framework

Abstract

We report how supramolecular host–guest assembly can be leveraged to close the gap between soluble polyoxometalates and functional solid-state materials. A polyoxovanadate cluster with specific metal binding sites is used as a functional building block for site-specific linkage by potassium cations into a hierarchically structured 3D framework. Mass spectrometric analyses provide initial insights into solution self-assembly and structure formation.

Graphical abstract: Supramolecular assembly of a hierarchically structured 3D potassium vanadate framework

Supplementary files

Article information

Article type
Communication
Submitted
17 Мам. 2021
Accepted
25 Мам. 2021
First published
25 Мам. 2021

CrystEngComm, 2021,23, 3946-3950

Supramolecular assembly of a hierarchically structured 3D potassium vanadate framework

S. Greiner, M. Anjass and C. Streb, CrystEngComm, 2021, 23, 3946 DOI: 10.1039/D1CE00661D

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