Issue 23, 2019

A reduction series of neodymium supported by pyridine(diimine) ligands

Abstract

The synthesis of a redox series of neodymium species bearing the redox active pyridine(diimine) ligand, MesPDIMe, is reported. Spectroscopic and structural characterization supports each compound has a Nd(III) centre, with the MesPDIMe ligand existing in four oxidation states.

Graphical abstract: A reduction series of neodymium supported by pyridine(diimine) ligands

Supplementary files

Article information

Article type
Communication
Submitted
14 Ақп. 2019
Accepted
08 Сәу. 2019
First published
25 Сәу. 2019

Dalton Trans., 2019,48, 8021-8025

Author version available

A reduction series of neodymium supported by pyridine(diimine) ligands

S. S. Galley, S. A. Pattenaude, R. F. Higgins, C. J. Tatebe, D. A. Stanley, P. E. Fanwick, M. Zeller, E. J. Schelter and S. C. Bart, Dalton Trans., 2019, 48, 8021 DOI: 10.1039/C9DT00679F

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