Issue 35, 2019

Design and reactivity of pentapyridyl metal complexes for ammonia oxidation

Abstract

Oxidation of NH3 to N2 by pentapyridyl metal complexes via hydrogen atom abstraction was investigated computationally. Quantum chemical analysis reveals insights on orbital symmetry requirements for efficient NH3 oxidation. The most promising complex, [(PY5)Mo(NH3)]2+, was studied experimentally. It shows conversion of NH3 to N2 upon treatment with 2,4,6-tri-tert-butylphenoxyl radical.

Graphical abstract: Design and reactivity of pentapyridyl metal complexes for ammonia oxidation

Supplementary files

Article information

Article type
Communication
Submitted
13 Ақп. 2019
Accepted
04 Сәу. 2019
First published
08 Сәу. 2019

Chem. Commun., 2019,55, 5083-5086

Author version available

Design and reactivity of pentapyridyl metal complexes for ammonia oxidation

S. I. Johnson, S. P. Heins, C. M. Klug, E. S. Wiedner, R. M. Bullock and S. Raugei, Chem. Commun., 2019, 55, 5083 DOI: 10.1039/C9CC01249D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements