Issue 33, 2009
From the journal:

Chemical Communications

Phosphabarrelene-modified Rh-catalysts: a new and selective route towards hydroxy-functionalized bicyclic imidazolesvia tandem reactions†‡

Patrick S. Bäuerlein,a   Ismael Arenas Gonzalez,a   Jarno J. M. Weemers,a   Martin Lutz,b   Anthony L. Spek,b   Dieter Vogta  and  Christian Müller*a  

* Corresponding authors

a Schuit Institute of Catalysis, Laboratory for Homogeneous Catalysis, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands
E-mail: c.mueller@tue.nl
Fax: +31 40 2455054
Tel: +31 40 2474679

b Bijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Utrecht University, 3584 CH Utrecht, The Netherlands

Abstract

8-Hydroxy-6-methyl-5,6,7,8-tetrahydroimidazo[1,2-a]pyridine was formed selectively in high yields from N-(β-methallyl)imidazole by a tandem hydroformylation–cyclization sequence, representing a novel one-pot catalytic synthesis of bicyclic imidazole derivatives.

Graphical abstract: Phosphabarrelene-modified Rh-catalysts: a new and selective route towards hydroxy-functionalized bicyclic imidazoles via tandem reactions

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Article information

DOI
https://doi.org/10.1039/B911612E
Article type
Communication
Submitted
12 Мау. 2009
Accepted
07 Шіл. 2009
First published
23 Шіл. 2009

Chem. Commun., 2009, 4944-4946

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Phosphabarrelene-modified Rh-catalysts: a new and selective route towards hydroxy-functionalized bicyclic imidazoles via tandem reactions

P. S. Bäuerlein, I. A. Gonzalez, J. J. M. Weemers, M. Lutz, A. L. Spek, D. Vogt and C. Müller, Chem. Commun., 2009, 4944 DOI: 10.1039/B911612E

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