View PDF Version
 
DOI: 10.1039/A808777F (Paper) Reference Section for: Chem. Commun., 1999, 177-178

Structural isomers of M(dca)2 molecule-based magnets. Crystal structure of tetrahedrally coordinated sheet-like β-Zn(dca)2 and β-Co/Zn(dca)2, and the octahedrally coordinated rutile-like α-Co(dca)2, where dca– = dicyanamide, N(CN)2–, and magnetism of β-Co(dca)2

(Note: The full text of this document is currently only available in the PDF Version )

Paul Jensen, Stuart R. Batten, Gary D. Fallon, Boujemaa Moubaraki, Keith S. Murray and David J. Price

Abstract

β-Zn(dca)2 and 0.12% Co(II) doped β-Zn(dca)2 contain tetrahedrally coordinated metal ions within a corrugated sheet network structure [dca = dicyanamide, N(CN)2–], β-Co(dca)2 is a spin-canted antiferromagnet (TN = 9 K), while the rutile-like octahedral α-form is a ferromagnet.

References

  1. S. R. Batten, P. Jensen, B. Moubaraki, K. S. Murray and R. Robson, Chem. Commun., 1998, 439 RSC.
  2. K. S. Murray, S. R. Batten, B. Moubaraki, D. J. Price and R. Robson, Mol. Cryst. Liq. Cryst., in press Search PubMed.
  3. C. Kepert and M. Kurmoo, Mol. Cryst. Liq. Cryst., in press Search PubMed.
  4. C. R. Kmety, J. L. Manson, Q. Huang, J. W. Lynn, R. W. Erwin, J. S. Miller and A. J. Epstein, Mol. Cryst. Liq. Cryst., in press Search PubMed.
  5. H. Köhler, Z. Anorg. Allg. Chem., 1964, 331, 237 CrossRef.
  6. A. Escuer, R. Vicente, M. A. S. Goher and F. A. Mautner, Inorg. Chem., 1997, 36, 3440 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.