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DOI: 10.1039/A807990K (Paper) Reference Section for: Chem. Commun., 1999, 193-194

Confinement of C70 in an extended saddle shaped nickel(II) macrocycle

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Peter D. Croucher, Jodie M. E. Marshall, Peter J. Nichols and Colin L. Raston

Abstract

Saddle shaped {2,3,6,8,11,12,15,17-octamethyldibenzo-[b,i]1,4,8,11-tetraaza(1,4)annulene}nickel(II), Ni(OMTAA),acts as a heterotropic divergent receptor molecule with C70 forming a 1:1 complex in the solid state, where the extended supramolecular array consists of zigzag alternating C70–Ni(OMTAA) chains and corrugated sheets of close contact C70 molecules.

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