Greatly enhanced optical anisotropy in thiophosphates inspired by rational coupling of tetrahedra and ethane-like [P2S6]4− groups

Ning Zhao, Dazhi Lu, Jingjing Xu, Kui Wu, Haohai Yu and Huaijin Zhang

Inorg. Chem. Front., 2024, 11, 4603
DOI: 10.1039/D4QI00883A

Na6Sn3P4S16: Sn(ii)-chelated PS4 groups inspired an ultra-strong SHG response

Chenyao Zhao, Bingbing Zhang, Xinyu Tian, Guoqiang Zhou, Jingjing Xu and Kui Wu

Inorg. Chem. Front., 2023, 10, 5726
DOI: 10.1039/D3QI01257C

Ga(IO3)3: a mid-IR nonlinear optical iodate with balanced performance between band gap and second harmonic generation response

Dandan Wang, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Zhanggui Hu and Yicheng Wu

J. Mater. Chem. C, 2023, 11, 10828
DOI: 10.1039/D3TC01570J

MB3P2S10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B6P4S20] T3-supertetrahedra

Jiazheng Zhou, Xin Su, Ling Luo, Junjie Li and Feng Yu

Dalton Trans., 2023, 52, 11401
DOI: 10.1039/D3DT01496G

Rb2CdSi4S10: novel [Si4S10] T2-supertetrahedra-contained infrared nonlinear optical material with large band gap

Jiazheng Zhou, Zhongxu Fan, Kewang Zhang, Zhihua Yang, Shilie Pan and Junjie Li

Mater. Horiz., 2023, 10, 619
DOI: 10.1039/D2MH01200F

Na6Mg3P4S16 and RbMg2PS4Cl2: two Mg-based thiophosphates with ultrawide bandgaps resulting from [MgS6] and [MgSxCl6−x] octahedra

Yi Huang, Dongdong Chu, Xueling Hou, Guangmao Li and Yong Zhang

Dalton Trans., 2024, 53, 866
DOI: 10.1039/D3DT03637E

Quaternary alkaline-earth metal thiophosphate SrAgPS4: syntheses, structures, and optical properties

Wenhao Xing, Jian Tang, Fei Liang, Chunlan Tang, Jieyun Wu, Wenlong Yin, Bin Kang and Jianguo Deng

Dalton Trans., 2023, 52, 6915
DOI: 10.1039/D3DT00793F

Effects of different groups on phase-matching and SHG in “3+4” Pn materials

Chaoyi Zhu and Guojie Jin

Physica B: Condensed Matter, 2024, 691, 416298
DOI: 10.1016/j.physb.2024.416298

Functional assembly and modification of nonlinear optical fundamental motifs in phosphates

Fan Liu, Pifu Gong, Zheshuai Lin and Lei Kang

Coordination Chemistry Reviews, 2025, 526, 216349
DOI: 10.1016/j.ccr.2024.216349

Clamping effect driven design and fabrication of new infrared birefringent materials with large optical anisotropy

Linan Wang, Chenchen Tu, Hongbo Gao, Jiazheng Zhou, Hongshan Wang, Zhihua Yang, Shilie Pan and Junjie Li

Sci. China Chem., 2023, 66, 1086
DOI: 10.1007/s11426-022-1452-8

Influence of Cation-Size Effects of Alkaline Earth (Ae) Metals on Dimensionality and Optical Anisotropy Regulation in K4AeP2S8 Thiophosphates

Xinyu Tian, Ning Zhao, Kui Wu, Jingjing Xu, Dazhi Lu, Haohai Yu and Huaijin Zhang

Inorg. Chem., 2024, 63, 8294
DOI: 10.1021/acs.inorgchem.4c00608

KREP2S6 (RE = Sm, Gd, Tb, Dy): A Series of Polar Rare-Earth Thiophosphates with High Laser-Induced Damage Thresholds and Moderate Nonlinear-Optical Responses Synergistically Contributed by Isolated P2S6 Units and {[RE2S15]24–}∞ Layers

Chen-Yi Zhao, Wen-Dong Yao, Ming-Yang Li, Wenfeng Zhou, Wenlong Liu and Sheng-Ping Guo

Inorg. Chem., 2024, 63, 4017
DOI: 10.1021/acs.inorgchem.4c00131

Eu(II)4Eu(III)2Ge3S11O2: a Single‐Element Mixed‐Valence Engineering Breakthrough for Strongly Enhanced Nonlinearity and Anisotropy in Rare‐Earth Oxysulfides

Jingjing Xu, Yan Xiao, Dazhi Lu, Bingbing Zhang, Kui Wu, Haohai Yu and Huaijin Zhang

Small, 2025, 21
DOI: 10.1002/smll.202506609

Salt-inclusion chalcogenides: Double functional moieties design strategy toward excellent nonlinear optical materials

Chao-Hong Xie, Bin-Wen Liu and Guo-Cong Guo

Chinese Journal of Structural Chemistry, 2023, 42, 100029
DOI: 10.1016/j.cjsc.2023.100029

A Congruent-Melt Infrared Nonlinear Optical Crystal Na4SrAs2S8

Zhihui Xiong, Aoge Yao, Zhixi Li, Xianghe Meng, Qian Wu, Guowei Deng, Lei Kang and Mingjun Xia

Inorg. Chem., 2024, 63, 14816
DOI: 10.1021/acs.inorgchem.4c02840

KREP2Se6 (RE = Sm, Gd, Tb): The First Rare‐Earth Selenophosphates with Remarkable Nonlinear Optical Activities Realized by Synergistic Effect of RE‐ and P‐Based Motifs

Zi‐Xia Chen, Chen‐Yi Zhao, Xiao‐Hui Li, Wen‐Dong Yao, Wenlong Liu and Sheng‐Ping Guo

Small, 2023, 19
DOI: 10.1002/smll.202206910

The compatibly large nonlinear optical effect and high laser-induced damage threshold in a thiophosphate CsInP2S7 constructed with [P2S7]4- and [InS6]9-

Mengjia Luo, Xiaohui Li, Xingxing Jiang, Zheshuai Lin and Zhengyang Zhou

Chinese Chemical Letters, 2024, 35, 109108
DOI: 10.1016/j.cclet.2023.109108