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Copper‐Catalyzed Enantioselective Hydrophosphorylation of Unactivated Alkynes

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Two-Step Substitution Reaction of Phosphonates Carrying a Binaphthyl Group with Grignard Reagents Leading to the Formation of P-Chirogenic Phosphine Oxides

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Nickel‐Catalyzed Asymmetric Synthesis of P‐Stereogenic Phosphanyl Hydrazine Building Blocks

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Metal‐Catalyzed Enantioselective Hydrophosphorylation Reactions

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Pd-Catalyzed Asymmetric Allenylation of Secondary Phosphine Oxides with Enyne-Type Propargylic Carbamates for the Construction of Chiral Allenyl Phosphine Oxides

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Rhodium‐Catalyzed Asymmetric Access to P‐Chiral Triarylphosphine Oxides via Insertion of P─H Bonds into Diazonaphthoquinones

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Advances in Catalytic Asymmetric Hydrogen-Phosphine/Phosphorus Functionalization of Unsaturated Carbon-Carbon Bonds

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Palladium‐Catalyzed Enantio‐ and Regioselective Ring‐Opening Hydrophosphinylation of Methylenecyclopropanes

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Asymmetric Synthesis of Chiral‐at‐P Alkenylphosphonamidates through Nickel‐Catalyzed C−P Coupling of Phosphoramidites and Alkenyl Halides

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P‐Chiral Organophosphorus Compounds: Synthesis, Mechanism, and Applications

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Nickel-Catalyzed Nucleophilic Substitution of Cyclopropenes by Secondary Phosphines

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Copper‐Catalyzed Dynamic Kinetic Asymmetric P−C Coupling of Secondary Phosphine Oxides and Aryl Iodides

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Diastereoselective and Enantioselective Hydrophosphinylations of Conjugated Enynes, Allenes and Dienes via Synergistic Pd/Co Catalysis

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Additive-Controlled Regioswitching in Ni-Catalyzed Enantioselective Hydrophosphination of Unactivated Alkenes

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Earth Abundant Transition Metal Catalysts: New and Efficient Tools for Hydrophosphination and Oxyphosphination of Alkenes and Alkynes

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Ligand-Enabled Cu-Catalyzed Stereoselective Synthesis of P-Stereogenic ProTides

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Enantioselective Synthesis of H‐Phosphinamidates

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Enantioselective Synthesis of H‐Phosphinamidates

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Pd-catalyzed enantioselective and regioselective asymmetric hydrophosphorylation and hydrophosphinylation of enynes

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Asymmetric Intramolecular Hydroamination to Construct Diverse N–N/C–N Indole Atropisomers via Cooperative Pd(0) and Chiral Phosphoric Acid Catalysis

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Palladium-Catalyzed Regio- and Enantioselective Hydrophosphination of gem-Difluoroallenes

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Palladium‐Catalyzed Enantio‐ and Regioselective Ring‐Opening Hydrophosphinylation of Methylenecyclopropanes

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Catalytic Asymmetric Hydrophosphinylation of 2‐Vinylazaarenes to Access P‐Chiral 2‐Azaaryl‐Ethylphosphine Oxides

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Copper‐Catalyzed Enantioselective Hydrophosphorylation of Unactivated Alkynes

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Recent Advances in Transition Metal‐Catalyzed Asymmetric Synthesis of P‐chiral Organophosphorus Compounds (2020–Present)

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Computational Study Revealing the Mechanistic Origin of Distinct Performances of P(O)–H/OH Compounds in Palladium-Catalyzed Hydrophosphorylation of Terminal Alkynes: Switchable Mechanisms and Potential Side Reactions

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Dynamic coordination drives regiodivergent dienylation of propargylic esters with phosphine oxides

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Chinese Chemical Letters, 2025, 112188
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Recent Advances in Asymmetric Synthesis of P-Chiral Phosphine Oxides

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Advances in Mechanistic Studies of Metal-Catalyzed Hydrophosphinylation of Non-Activated Alkynes

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Nickel‐Catalyzed Asymmetric Synthesis of P‐Stereogenic Phosphanyl Hydrazine Building Blocks

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Nickel-Catalyzed Direct Enantioselective Alkynylation of Alkynyl Bromide with Secondary Phosphine Oxides

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Synthesis of P‐Stereogenic Phosphine Oxides via Nickel‐Catalyzed Asymmetric Cross‐Coupling of Secondary Phosphine Oxides with Alkenyl and Aryl Bromides

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Ni-catalyzed regiodivergent hydrophosphorylation of enynes

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Asymmetric Synthesis of Chiral‐at‐P Alkenylphosphonamidates through Nickel‐Catalyzed C−P Coupling of Phosphoramidites and Alkenyl Halides

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Ligand-Enabled Cu-Catalyzed Stereoselective Synthesis of P-Stereogenic ProTides

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Nickel-catalyzed kinetic resolution to achieve P-chiral phosphine oxides and sec-phosphine oxides

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Nickel-Catalyzed Asymmetric Synthesis of Ambiphilic Secondary Phosphine Oxides

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Pd/Co‐Catalyzed Asymmetric Hydrophosphinylation of Conjugated Enynes to Access Fully C(sp2)‐Substituted P(V) Center

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DFT Studies on Pd/Xiao‐Phos‐Catalyzed Asymmetric Arylation of Secondary Phosphine Oxides

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Nickel-catalysed enantioselective hydrosulfenation of alkynes

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Synthesis of Chiral α‐Substituted β‐Aminophosphine Derivatives through Asymmetric Hydrophosphinylation Utilizing Secondary Phosphine Sulfides

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Chemistry An Asian Journal, 2022, 17
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Construction of Tetrasubstituted α‐Amino‐ and α‐Alkoxy Phosphine Oxides via Pd‐Catalyzed Regio‐ and Enantioselective Hydrophosphinylation of Dienes

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Nickel-Catalyzed Asymmetric Arylation of H-Phosphinates

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Palladium-Catalyzed Sequential Hydroamination and Hydroxylation of 1,3-Enynes with 2-Aminophenols

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Synthesis of P‐Stereogenic Compounds by Transition Metal‐Catalyzed Asymmetric Transformation of H−P(O) Compounds: Progress, Challenges, and Prospects

Kang Ding and Bo Su

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Ligand-controlled regiodivergent and enantioselective hydrophosphorylation of styrenes by palladium

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Nickel-catalyzed switchable 1,3-dienylation and enantioselective allenylation of phosphine oxides

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Enantioselective Synthesis of Five to Eight‐Membered P‐Stereogenic Benzo‐Fused Heterocycles via Copper‐Catalyzed Dynamic Kinetic Resolution

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NiII-Catalyzed Enantioselective Anti-Markovnikov Hydrophosphination of Unactivated Alkynes

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ACS Catal., 2023, 13, 6994
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Electrochemically Enabled Hydroxyphosphorylation of 1,3-Enynes to Access Phosphinyl-Substituted Propargyl Alcohols

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Synthesis of P‐Stereogenic Phosphine Oxides via Nickel‐Catalyzed Asymmetric Cross‐Coupling of Secondary Phosphine Oxides with Alkenyl and Aryl Bromides

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Diastereoselective and Enantioselective Hydrophosphinylations of Conjugated Enynes, Allenes and Dienes via Synergistic Pd/Co Catalysis

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Copper‐Catalyzed Dynamic Kinetic Asymmetric P−C Coupling of Secondary Phosphine Oxides and Aryl Iodides

Jie Kang, Kang Ding, Si‐Mu Ren and Bo Su

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Catalytic Asymmetric Hydrophosphinylation of 2‐Vinylazaarenes to Access P‐Chiral 2‐Azaaryl‐Ethylphosphine Oxides

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Organocatalytic Diastereoselective (4 + 1) Cycloaddition of o-Hydroxyphenyl-Substituted Secondary Phosphine Oxides

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