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Recent advances in carbon atom addition for ring-expanding single-atom skeletal editing

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Tunable Regiodivergent Reactivity of N-Allenamides with Silacyclobutanes via Palladium Catalysis in the Synthesis of Silacyclic β-Aminosilanes

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Synthesis of cyclic organosilicon compounds by palladium-catalyzed reactions of 2-silylaryl triflates

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Copper-Catalyzed Synthesis of S–S Bond-Containing Silanols from SCBs and Trisulfide-1,1-dioxides

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Unconventional Insertions of Internal Alkynes into a Mixed-Valent Silaiminyl-Silylene

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Enantioselective synthesis of silicon-stereogenic siladihydrofuran via copper-catalyzed Si-C bond cleavage

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Rhodium-Catalyzed Chemodivergent Synthesis of Organosilicons Enabled by Controllable C–Si Bond Activation

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Titanium‐Catalyzed Reaction of Silacyclobutanes with Alkenes: Mimicking the Reactivity and Reversing the Selectivity Towards Late Transition Metals

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Chemodivergent Construction of Seven-Membered Silacycles via Palladium-Catalyzed Ring Expansion from 4- to 7-Membered Rings

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Modular and Regioselective Synthesis of Eight-Membered Benzosilacycles Enabled by Ring Expansion of Silacyclobutanes with Aryl Halides and Alkynes

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Lewis Base-Catalyzed Dynamic Kinetic Asymmetric Transformation of Racemic Chlorosilanes en Route to Si-Stereogenic Silylethers

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Nickel-Catalyzed [4＋2] Cyclization of Benzosilacyclobutenes and Acylsilanes

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Pd-catalyzed intermolecular Si–O formation via Si–C activation

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Construction of <italic>Si</italic>-stereogenic organosilanes from chlorosilanes

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Palladium-catalyzed double activation of Si-C(sp3) bond of benzosilacyclobutenes synergized with unexpected olefin migration and ring-opening hydrolysis

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Recent Advances in Transition Metal-Catalyzed C—Si Bond Cleavage of Silacyclobutanes

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Ring Expansion toward Disila‐carbocycles via Highly Selective C−Si/C−Si Bond Cross‐Exchange

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Rhodium-Catalyzed (Asymmetric) Annulation of Silacyclobutanes with Bicyclic Olefins via C–Si Bond Activation

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Synthesis of Alkynylsilanes: A Review of the State of the Art

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State-of-the-Art Advances in Enantioselective Transition-Metal-Mediated Reactions of Silacyclobutanes

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Enantioselective Synthesis of Axially Chiral Silacyclohexylidene Oxime Ethers by Chiral Phosphoric Acid Catalysis

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Rhodium-Catalyzed Hydrolytic Cleavage of the Silicon–Carbon Bond of Silacyclobutanes to Access Silanols

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Photocatalytic site-selective radical C(sp3)–H aminoalkylation, alkylation and arylation of silanes

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Intramolecular Ring Expansion of 3-Silaazetidine with Alkynes Enabled by Pd-Catalyzed Si–C Bond Activation

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Palladium-catalyzed desymmetric coupling reaction between silacyclobutanes and terminal alkynes for the synthesis of silicon-stereogenic allyl vinylsilanes

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Nickel‐Catalyzed Reductive Protocol to Access Silacyclobutanes with Unprecedented Functional Group Tolerance

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Palladium‐Catalyzed (4+2) Annulations of Silacyclobutanes and Activated Ketones

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Nickel‐Catalyzed Reductive Protocol to Access Silacyclobutanes with Unprecedented Functional Group Tolerance

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Regiodivergent Synthesis of Eight-Membered Benzosilacycles via Palladium-Catalyzed Alkenyl C(sp2)–H Activation

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Palladium-Catalyzed Reactions of 2-Silylaryl Triflates for the Synthesis of Cyclic Organosilanes

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Palladium‐Catalyzed Ring Expansion of Benzosilacyclobutenes: Ligand Substituent Effects on Stereodivergent Catalysis

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A Novel Photocatalytic Ring Opening Reaction of Silacyclobutanes with Alkenes

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3‐Amido‐benzo[b]silines: Straightforward Modular 2‐Step Synthesis and Photophysical Properties

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Regio- and Chemoselective Access to Borylmethyl-Substituted Silacyclobutanes via Copper-Catalyzed Borylative Cyclization

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Photo-induced ring-maintaining hydrosilylation of unactivated alkenes with hydrosilacyclobutanes

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Enantioselective construction of silicon-stereogenic vinylsilanes from simple alkenes

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Photocatalyzed Thiosulfonylation of Sila-enynes with Thiosulfonates

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Recent Progress in the Construction of Silacycles by Transition- Metal-Catalyzed C—H Silylation

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Strain‐Driven, Non‐Catalysed Ring Expansion of Silicon Heterocycles

Maximilian P. Müller and Alexander Hinz

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Ring Expansion toward Disila‐carbocycles via Highly Selective C−Si/C−Si Bond Cross‐Exchange

Min Liu, Nuo Yan, Haowen Tian, Bo Li and Dongbing Zhao

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Rhodium-Catalyzed Addition of (Trialkylsilyl)arenes to Electrophiles via π-Coordination-Driven C–Si Bond Activation

Yunzhi Lin and Hang Shi

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Recent Advances in the Transformation of Difluorocyclopropenes★

Huang Jiapian, Liu Fei and Wu Jie

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Titanium‐Catalyzed Reaction of Silacyclobutanes with Alkenes: Mimicking the Reactivity and Reversing the Selectivity Towards Late Transition Metals

Yaqiong Wang, Jiong Zhang, Fang Wang and Lipeng Wu

Angew Chem Int Ed, 2025, 64
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