Probing the guest-binding preference of three structurally similar and conformationally adaptive macrocycles

Hongxin Chai, Zhi-Sheng Pan, Liu-Pan Yang, Shan He, Fangfang Pan, Kari Rissanen and Wei Jiang

Chem. Commun., 2019, 55, 7768
DOI: 10.1039/C9CC03341F

Synthesis of a large-cavity carbazole macrocycle for size-dependent recognition

Ming Dong, Xiu Liu, Zhi-Yuan Zhang, Chengmao Yu, Bochao Huo and Chunju Li

Chem. Commun., 2022, 58, 2319
DOI: 10.1039/D1CC06788E

Facile surface functionalization of upconversion nanoparticles with phosphoryl pillar[5]arenes for controlled cargo release and cell imaging

Xu Wang, Jie Yang, Xiujuan Sun, Hongliang Yu, Fei Yan, Kamel Meguellati, Ziyong Cheng, Haiyuan Zhang and Ying-Wei Yang

Chem. Commun., 2018, 54, 12990
DOI: 10.1039/C8CC08168A

Rapid gel-to-sol transition triggered by a photoacid generator under low-power light

Pengchong Xue, Jipeng Ding, Ming Jin and Ran Lu

J. Mater. Chem. C, 2017, 5, 5299
DOI: 10.1039/C7TC01028A

Benchmark selectivity p-xylene separation by a non-porous molecular solid through liquid or vapor extraction

Na Sun, Shi-Qiang Wang, Ruqiang Zou, Wen-Gang Cui, Anqi Zhang, Tianzhen Zhang, Qi Li, Zhan-Zhong Zhuang, Ying-Hui Zhang, Jialiang Xu, Michael J. Zaworotko and Xian-He Bu

Chem. Sci., 2019, 10, 8850
DOI: 10.1039/C9SC02621E

Bridged chemistry of macrocyclic arenes: from sp3-carbon bridges to π-conjugation and heteroatom bridging

Xu-Xu Jia, Tai-Bao Wei, Qi Lin, Bingbing Shi, Hong Yao, Wen-Juan Qu and Jin-Fa Chen

Chem. Commun., 2026, 62, 1087
DOI: 10.1039/D5CC05771J

Effects of side chains of oxatub[4]arene on its conformational interconversion, molecular recognition and macroscopic self-assembly

Liu-Pan Yang, Fei Jia, Fangfang Pan, Zhi-Sheng Pan, Kari Rissanen and Wei Jiang

Chem. Commun., 2017, 53, 12572
DOI: 10.1039/C7CC07630D

Fluorescence indicator displacement detection based on pillar[5]arene-assisted dye deprotonation

Bin Hua, Li Shao, Guocan Yu and Feihe Huang

Chem. Commun., 2016, 52, 10016
DOI: 10.1039/C6CC04919B

Nitric oxide-containing supramolecular polypeptide nanomedicine based on [2]biphenyl-extended-pillar[6]arenes for drug resistance reversal

Yue Ding, Yuxuan Ma, Lvming Zhu, Yue Xu, Chenwei Wang, Bing Lu, Yang Wang, Chang Du and Yong Yao

J. Mater. Chem. B, 2022, 10, 6181
DOI: 10.1039/D2TB01127A

Conjugated macrocycle polymers

Zheng Li and Ying-Wei Yang

Polym. Chem., 2021, 12, 4613
DOI: 10.1039/D1PY00759A

2,2′-Biphen[n]arenes (n = 4–8): one-step, high-yield synthesis, and host–guest properties

Lu Dai, Zhi-Jun Ding, Lei Cui, Jian Li, Xueshun Jia and Chunju Li

Chem. Commun., 2017, 53, 12096
DOI: 10.1039/C7CC06767D

Macrocyclic membranes: from liquid to solid state

Lei Yang, Cheng-Yu Zhang, Hao-Ling Zhang, Qing-Yang Zhang, Jong Seung Kim and Yue Sun

Chem. Soc. Rev., 2025, 54, 7377
DOI: 10.1039/D5CS00100E

Hybrid[4]arenes with anthracene units and tuneable cavities

Tomasz Boinski and Agnieszka Szumna

New J. Chem., 2017, 41, 3387
DOI: 10.1039/C7NJ00039A

A water-soluble cationic [2]biphenyl-extended pillar[6]arene: synthesis, host–guest interaction with hemin and application in chemodynamic/photodynamic cancer therapy

Yan Cai, Yue Zhang, Xufeng Liang, Chunlin Deng, Jianxia Zhang, Haotian Wang, Hui Duan and Yong Yao

Chem. Commun., 2025, 61, 5333
DOI: 10.1039/D5CC00627A

Influence of crystallization solvents on the crystal structures and supramolecular assemblies of a [2]naphthyl-extended pillar[6]arene

Randa Abd Almoaeen, Mickey Vinodh, Fatemeh H. Alipour and Talal F. Al-Azemi

CrystEngComm, 2026, 28, 1331
DOI: 10.1039/D5CE01118C

Molecular recognition and adsorptive separation of m-xylene by trianglimine crystals

Avishek Dey, Santanu Chand, Munmun Ghosh, Monerah Altamimy, Bholanath Maity, Prashant M. Bhatt, Imtiyaz Ahmad Bhat, Luigi Cavallo, Mohammed Eddaoudi and Niveen M. Khashab

Chem. Commun., 2021, 57, 9124
DOI: 10.1039/D1CC03531B

Synthesis of a water-soluble 2,6-helic[6]arene derivative and its strong binding abilities towards quaternary phosphonium salts: an acid/base controlled switchable complexation process

Geng-Wu Zhang, Yuchun Han, Ying Han, Yilin Wang and Chuan-Feng Chen

Chem. Commun., 2017, 53, 10433
DOI: 10.1039/C7CC05489K

Reversible encapsulation and release of fullerenes using calix[n]phenoxazines

Lu Wang, Yunxiao Li, Xin Qu, Da Ma, M. Zubair Iqbal, Xiangdong Kong and Lijun Mao

Org. Biomol. Chem., 2024, 22, 9053
DOI: 10.1039/D4OB01569J

Three-dimensional supramolecular polymerization based on pillar[n]arenes (n = 5, 6) and halogen bonding interactions

Chengyou Han, Dezhi Zhao and Shengyi Dong

Chem. Commun., 2018, 54, 13099
DOI: 10.1039/C8CC07993E

Facile synthesis of heterogeneous macrocycles for intramolecular energy transfer

Ao Liu, Xin Meng, Chen-Chen Shen, Zhi-Yuan Zhang and Chunju Li

Chem. Commun., 2022, 58, 12684
DOI: 10.1039/D2CC04673C

New opportunities in synthetic macrocyclic arenes

Jia-Rui Wu and Ying-Wei Yang

Chem. Commun., 2019, 55, 1533
DOI: 10.1039/C8CC09374A

Recent advances in the synthesis and applications of macrocyclic arenes

Xiao-Ni Han, Ying Han and Chuan-Feng Chen

Chem. Soc. Rev., 2023, 52, 3265
DOI: 10.1039/D3CS00002H

Pillar[n]arene–calix[m]arene hybrid macrocyclic structures

Zhaona Liu, Bing Li, Leqian Song and Huacheng Zhang

RSC Adv., 2022, 12, 28185
DOI: 10.1039/D2RA05118D

Macrocycle formation-mediated augmentation in reactive oxygen species production

Ao Liu, Youtao Xin, Yong-Kang Zhu, Yuan-Hang Jin, Yue Yang, Hongzhu Chen, Meng-Hao Li, Xin-Yue Lou, Xin Wang, Hui Gao and Ying-Wei Yang

Chem. Sci., 2025, 16, 20968
DOI: 10.1039/D5SC06637A

Macrocyclic host molecules with aromatic building blocks: the state of the art and progress

Qiang Shi, Xuping Wang, Bing Liu, Panyu Qiao, Jing Li and Leyong Wang

Chem. Commun., 2021, 57, 12379
DOI: 10.1039/D1CC04400A

An amphiphilic [2]biphenyl-extended pillar[6]arene: Synthesis, controllable self-assembly in water and application in cell-imaging

Tingting Chen, Jian Wang, Ruowen Tang, Yuying Huang, Qin Zhao and Yong Yao

Chinese Chemical Letters, 2023, 34, 108088
DOI: 10.1016/j.cclet.2022.108088

Regioselective Synthesis of Methylene-Bridged Naphthalene Oligomers and Their Host–Guest Chemistry

San-Jiang Pan, Gang Ye, Fei Jia, Zhenfeng He, Hua Ke, Huan Yao, Zhi Fan and Wei Jiang

J. Org. Chem., 2017, 82, 9570
DOI: 10.1021/acs.joc.7b01579

Imidazolium Ionic Liquid-Functionalized Extended Pillar[6]Arene with High Selectivity for Gas-Chromatographic Separations

Haolong Qi, Haixin Liu, Xin Shen, Yuanyuan Zhang, Xiang Xu, Kexin Yang, Linyi Wei, Yongrui He, Tao Sun and Zhiqiang Cai

J Anal Chem, 2026, 81, 345
DOI: 10.1134/S1061934825601586

Metal-organic frameworks for C6–C8 hydrocarbon separations

Zhaoqiang Zhang, Shing Bo Peh, Chengjun Kang, Kungang Chai and Dan Zhao

EnergyChem, 2021, 3, 100057
DOI: 10.1016/j.enchem.2021.100057

Regulating Host–Guest Interactions between Cucurbit[7]uril and Guests on Gold Surfaces for Rational Engineering of Gold Nanoparticles

Mingyang Zhang, Zhengjie Gong, Wenshuo Yang, Lunqiang Jin, Simin Liu, Shuai Chang and Feng Liang

ACS Appl. Nano Mater., 2020, 3, 4283
DOI: 10.1021/acsanm.0c00435

Insight into the syntheses, performances and mechanisms of organically modified adsorbents for mercury ion sensing and removal

Abdulkadir Tanimu and Khalid Alhooshani

Journal of Environmental Chemical Engineering, 2021, 9, 105833
DOI: 10.1016/j.jece.2021.105833

Recent Progress in Functional Materials for Selective Detection and Removal of Mercury(II) Ions

Dihua Dai, Jie Yang, Yan Wang and Ying‐Wei Yang

Adv Funct Materials, 2021, 31
DOI: 10.1002/adfm.202006168

Symmetrically Tetra‐functionalized Pillar[6]arenes Prepared by Fragment Coupling

Hong Zeng, Peiren Liu, Hao Xing and Feihe Huang

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202115823

Macrocycle‐Based Porous Organic Polymers for Separation, Sensing, and Catalysis

Zheng Li and Ying‐Wei Yang

Advanced Materials, 2022, 34
DOI: 10.1002/adma.202107401

Pyromellitic Diimide-Extended Pillar[6]arene: Synthesis, Structure, and Its Complexation with Polycyclic Aromatic Hydrocarbons

Fei Zeng, Lu Cheng, Guang-Chuan Ou, Lin-Li Tang and Man-Hua Ding

J. Org. Chem., 2022, 87, 3863
DOI: 10.1021/acs.joc.1c03096

Supramolecular Exchange Reaction in the Cavity of Naphthalene Diimides Extended‐Pillar[6]arene

Fei Zeng, Lin‐Li Tang, Shan‐Shan Tang, Hai‐Shan Tang and Man‐Hua Ding

Chemistry An Asian Journal, 2024, 19
DOI: 10.1002/asia.202400767

Stereoselective Synthesis of Pillar[4]arene[1]cis‐diepoxy‐p‐dione and X‐Ray Crystal Structure of Host–Guest System

Chengyou Han, Dezhi Zhao, Tian Li and Daofeng Sun

Chemistry An Asian Journal, 2017, 12, 2354
DOI: 10.1002/asia.201700791

BowtieArene: A Dual Macrocycle Exhibiting Stimuli‐Responsive Fluorescence

Sheng‐Nan Lei, Hongyan Xiao, Yi Zeng, Chen‐Ho Tung, Li‐Zhu Wu and Huan Cong

Angew Chem Int Ed, 2020, 59, 10059
DOI: 10.1002/anie.201913340

Host–guest behavior of pillar[n]arene-based supramolecular assemblies

Tan-Hao Shi, Shunsuke Ohtani, Kenichi Kato, Shixin Fa and Tomoki Ogoshi

Trends in Chemistry, 2023, 5, 537
DOI: 10.1016/j.trechm.2023.04.004

Pillararene-Inspired Macrocycles: From Extended Pillar[n]arenes to Geminiarenes

Jia-Rui Wu, Gengxin Wu and Ying-Wei Yang

Acc. Chem. Res., 2022, 55, 3191
DOI: 10.1021/acs.accounts.2c00555

Advances in diversified application of pillar[n]arenes

Liying Guo, Jinghua Du, Yirong Wang, Kaiyu Shi and Enqing Ma

J Incl Phenom Macrocycl Chem, 2020, 97, 1
DOI: 10.1007/s10847-020-00986-z

Orthogonal Design of a Water-Soluble meso-Tetraphenylethene-Functionalized Pillar[5]arene with Aggregation-Induced Emission Property and Its Therapeutic Application

Xueqi Tian, Minzan Zuo, Pengbo Niu, Krishnasamy Velmurugan, Kaiya Wang, Yue Zhao, Leyong Wang and Xiao-Yu Hu

ACS Appl. Mater. Interfaces, 2021, 13, 37466
DOI: 10.1021/acsami.1c07106

BowtieArene: A Dual Macrocycle Exhibiting Stimuli‐Responsive Fluorescence

Sheng‐Nan Lei, Hongyan Xiao, Yi Zeng, Chen‐Ho Tung, Li‐Zhu Wu and Huan Cong

Angewandte Chemie, 2020, 132, 10145
DOI: 10.1002/ange.201913340

Phenyl‐Extended Resorcin[4]arenes: Synthesis and Highly Efficient Iodine Adsorption

Dongxia Li, Gengxin Wu, Yong‐Kang Zhu and Ying‐Wei Yang

Angew Chem Int Ed, 2024
DOI: 10.1002/anie.202411261

A Water‐Soluble [2]Biphenyl‐Extended Pillar[6]arene

Jia‐Rui Wu, Chun‐Yu Wang, Yan‐Chun Tao, Yan Wang, Chunju Li and Ying‐Wei Yang

Eur J Org Chem, 2018, 2018, 1321
DOI: 10.1002/ejoc.201800112

Recent Applications of Pillararene‐Inspired Water‐Soluble Hosts

Yujie Zhu, Ya Gao, Julius Rebek and Yang Yu

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202404424

Host–Guest chemistry based on solid-state pillar[n]arenes

Shunsuke Ohtani, Kenichi Kato, Shixin Fa and Tomoki Ogoshi

Coordination Chemistry Reviews, 2022, 462, 214503
DOI: 10.1016/j.ccr.2022.214503

Biphenarenes, Versatile Synthetic Macrocycles for Supramolecular Chemistry

Wenjie Zhang, Wenzhi Yang and Jiong Zhou

Molecules, 2023, 28, 4422
DOI: 10.3390/molecules28114422

Phenyl‐Extended Resorcin[4]arenes: Synthesis and Highly Efficient Iodine Adsorption

Dongxia Li, Gengxin Wu, Yong‐Kang Zhu and Ying‐Wei Yang

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202411261

Desymmetrized pillar[8]arenes: High-yield synthesis, functionalization, and host-guest chemistry

Jie Yang, Xin-Yue Lou, Dihua Dai, Jingwei Shi and Ying-Wei Yang

Chinese Chemical Letters, 2025, 36, 109818
DOI: 10.1016/j.cclet.2024.109818

Synthesis of a Difunctionalized Pillar[5]arene with Hydroxyl and Amino Groups at A1/A2 Positions

Chengyou Han, Dezhi Zhao, Zhifeng Lü, Fengtao Zhan, Liangliang Zhang, Shengyi Dong and Lin Jin

Eur J Org Chem, 2019, 2019, 2508
DOI: 10.1002/ejoc.201900051

Molecular Design and Functional Engineering of POPs and MOFs for Advanced Radioactive Iodine Sequestration

Nowsheenah Farooq and Athar Adil Hashmi

ChemistrySelect, 2025, 10
DOI: 10.1002/slct.202504220

Synthesis and Structure of Pillar[m]arene[1]phthalimide and Pillar[m]arene[1]naphthalimide

Wan-Xia Liu, Jing Zeng, Wen-Hu Bao, Fan-Ping Xu, Lin-Li Tang, Man-Hua Ding and Fei Zeng

Org. Lett., 2025, 27, 1447
DOI: 10.1021/acs.orglett.4c04819

Cation-mediated sandwich formation between benzene and pillar[5]arene: a DFT study

Nabajit Sharmah and Pradip Kr. Bhattacharyya

Molecular Physics, 2019, 117, 734
DOI: 10.1080/00268976.2018.1540802

Synthetic Macrocycle Nanopore for Potassium-Selective Transmembrane Transport

Dan Qiao, Himanshu Joshi, Huangtianzhi Zhu, Fushi Wang, Yang Xu, Jia Gao, Feihe Huang, Aleksei Aksimentiev and Jiandong Feng

J. Am. Chem. Soc., 2021, 143, 15975
DOI: 10.1021/jacs.1c04910

Functional Materials with Pillarene Struts

Zheng Li and Ying-Wei Yang

Acc. Mater. Res., 2021, 2, 292
DOI: 10.1021/accountsmr.1c00042

Organic-Inorganic Hybrid Pillarene-Based Nanomaterial for Label-Free Sensing and Catalysis

Xin Wang, Zeng-Jie Liu, Eric H. Hill, Yuebing Zheng, Guanqi Guo, Yan Wang, Paul S. Weiss, Jihong Yu and Ying-Wei Yang

Matter, 2019, 1, 848
DOI: 10.1016/j.matt.2019.03.005

New macrocyclic arenes and beyond: synthesis, properties and applications

Ying Han, Xiao-Ni Han, Yu-Jie Long, Shuo Tong, Bin Li, Ao Liu, Wenhao Lin, Fei Zeng, Andrew C.-H. Sue, Liu-Pan Yang, Kang Cai, Hao Li, Leyong Wang, Ying-Wei Yang, Chun-Ju Li, Mei-Xiang Wang and Chuan-Feng Chen

Sci. China Chem., 2026, 69, 1064
DOI: 10.1007/s11426-025-3204-2

Pillararene-inspired arenes: Synthesis, properties and applications compared to the parent macrocycle

Sem Bleus and Wim Dehaen

Coordination Chemistry Reviews, 2024, 509, 215762
DOI: 10.1016/j.ccr.2024.215762

Pillararene‐Based Supramolecular Polymers for Adsorption and Separation

Zhuo‐Qin Wang, Xin Wang and Ying‐Wei Yang

Advanced Materials, 2024, 36
DOI: 10.1002/adma.202301721

Naphthol-based macrocyclic receptors

Liu-Pan Yang, Wei-Er Liu and Wei Jiang

Tetrahedron Letters, 2016, 57, 3978
DOI: 10.1016/j.tetlet.2016.07.077

Supramolecular Nanoplatform for Biofilm Eradication and Anti‐inflammatory by Phototherapies and Macrophage Repolarization

Jun Xie, Wenlong Huang, Shaoshuai Liu, Zepeng Cui, Baoxuan Huang, Jia Tian and Weian Zhang

Adv Healthcare Materials, 2025, 14
DOI: 10.1002/adhm.202501162

Symmetrically Tetra‐functionalized Pillar[6]arenes Prepared by Fragment Coupling

Hong Zeng, Peiren Liu, Hao Xing and Feihe Huang

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202115823

Molecular-scale drug delivery systems loaded with oxaliplatin for supramolecular chemotherapy

Jie Yang, Dihua Dai, Lianjun Ma and Ying-Wei Yang

Chinese Chemical Letters, 2021, 32, 729
DOI: 10.1016/j.cclet.2020.08.035

Macrocyclic Arenes‐Based Conjugated Macrocycle Polymers for Highly Selective CO2 Capture and Iodine Adsorption

Dihua Dai, Jie Yang, Yong‐Cun Zou, Jia‐Rui Wu, Li‐Li Tan, Yan Wang, Bao Li, Tong Lu, Bo Wang and Ying‐Wei Yang

Angew Chem Int Ed, 2021, 60, 8967
DOI: 10.1002/anie.202015162

Study on the Complexation Properties of Promellitic Diimide- Extended Pillar[6]aren and Carboxylate Guests

Lu Cheng, Fei Zeng and Xiaofeng Wang

Chinese Journal of Organic Chemistry, 2023, 43, 352
DOI: 10.6023/cjoc202206018

Separation performances of extended pillar[6]arenes, a new stationary phase for gas chromatography

Tao Sun, Yuanyuan Zhang, Haixin Liu, Xiang Xu, Zhiqiang Cai, Shaoqiang Hu, Xianming Liu, Maurizio Quinto and Shusheng Zhang

Talanta, 2025, 283, 127098
DOI: 10.1016/j.talanta.2024.127098

Stimuli-responsive fluorescent supramolecular polymer network based on a monofunctionalized leaning tower[6]arene

Zengjie Liu, Jiarui Wu, Chunyu Wang, Jie Yang, Yan Wang and Ying-Wei Yang

Chinese Chemical Letters, 2019, 30, 2299
DOI: 10.1016/j.cclet.2019.10.023

Separation of xylene isomers using metal-organic frameworks: Addressing challenges in the petrochemical industry

Ying Liu, Chao Wang, Qiwei Yang, Qilong Ren and Zongbi Bao

Coordination Chemistry Reviews, 2025, 523, 216229
DOI: 10.1016/j.ccr.2024.216229

Supramolecular Assembly-Induced Emission Enhancement for Efficient Mercury(II) Detection and Removal

Dihua Dai, Zheng Li, Jie Yang, Chunyu Wang, Jia-Rui Wu, Yan Wang, Dongmei Zhang and Ying-Wei Yang

J. Am. Chem. Soc., 2019, 141, 4756
DOI: 10.1021/jacs.9b01546

Macrocyclic Arenes‐Based Conjugated Macrocycle Polymers for Highly Selective CO2 Capture and Iodine Adsorption

Dihua Dai, Jie Yang, Yong‐Cun Zou, Jia‐Rui Wu, Li‐Li Tan, Yan Wang, Bao Li, Tong Lu, Bo Wang and Ying‐Wei Yang

Angewandte Chemie, 2021, 133, 9049
DOI: 10.1002/ange.202015162

Near-Ideal Xylene Selectivity in Adaptive Molecular Pillar[n]arene Crystals

Kecheng Jie, Ming Liu, Yujuan Zhou, Marc A. Little, Angeles Pulido, Samantha Y. Chong, Andrew Stephenson, Ashlea R. Hughes, Fumiyasu Sakakibara, Tomoki Ogoshi, Frédéric Blanc, Graeme M. Day, Feihe Huang and Andrew I. Cooper

J. Am. Chem. Soc., 2018, 140, 6921
DOI: 10.1021/jacs.8b02621

A conformationally adaptive macrocycle: conformational complexity and host–guest chemistry of zorb[4]arene

Liu-Pan Yang, Song-Bo Lu, Arto Valkonen, Fangfang Pan, Kari Rissanen and Wei Jiang

Beilstein J. Org. Chem., 2018, 14, 1570
DOI: 10.3762/bjoc.14.134

Separation and Detection of meta‐ and ortho‐Substituted Benzene Isomers by Using a Water‐Soluble Pillar[5]arene

Gengwu Zhang, Basem Moosa, Aiping Chen and Niveen M. Khashab

ChemPlusChem, 2020, 85, 1244
DOI: 10.1002/cplu.202000275

Effective Binding of Neutral Dinitriles by Pillar[4]arene[1]quinone both in Solution and in Solid State

Chengyou Han, Dezhi Zhao, Haiyu Li, Haibo Wang, Xu Huang and Daofeng Sun

ChemistrySelect, 2018, 3, 11
DOI: 10.1002/slct.201702793

Host‐Guest Complexations Between Pillar[6]arenes and Neutral Pentaerythritol Derivatives

Chengyou Han, Dezhi Zhao and Shengyi Dong