Issue 40, 2012
From the journal:

Chemical Communications

Kinetic effects of tartaric acid on the growth of chiral J-aggregates of tetrakis(4-sulfonatophenyl)porphyrin†‡

Maria Angela Castriciano,*a   Andrea Romeo,ab   Roberto Zagami,b   Norberto Micalic  and  Luigi Monsù Scolaro*ab  

* Corresponding authors

a CNR-ISMN, Istituto per lo Studio dei Materiali Nanostrutturati, 98166, V.le F. Stagno D'Alcontres 31, Messina, Italy
E-mail: castriciano@pa.ismn.cnr.it, lmonsu@unime.it

b Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, and C.I.R.C.M.S.B., University of Messina, V.le F. Stagno D'Alcontres 31, Vill. S. Agata, 98166 Messina, Italy

c CNR-IPCF, Istituto per i Processi Chimico-Fisici, 98158, V.le F. Stagno D'Alcontres 37, Messina, Italy

Abstract

The kinetics of growth for chiral J-aggregates of H4TPPS4 porphyrin have been investigated under different experimental conditions in the presence of tartaric acid. The observed rate constants and the anisotropy factor g show a defined dependence on the enantiomer used as a chiral templating agent.

Graphical abstract: Kinetic effects of tartaric acid on the growth of chiral J-aggregates of tetrakis(4-sulfonatophenyl)porphyrin

  • This article is part of the themed collection: Chirality
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Article information

DOI
https://doi.org/10.1039/C2CC00028H
Article type
Communication
Submitted
02 Jan 2012
Accepted
21 Mar 2012
First published
12 Apr 2012

Chem. Commun., 2012,48, 4872-4874

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Kinetic effects of tartaric acid on the growth of chiral J-aggregates of tetrakis(4-sulfonatophenyl)porphyrin

M. A. Castriciano, A. Romeo, R. Zagami, N. Micali and L. M. Scolaro, Chem. Commun., 2012, 48, 4872 DOI: 10.1039/C2CC00028H

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