Issue 27, 2010
From the journal:

Dalton Transactions

Thermal reaction of a (hydrido)(selenolato)platinum(ii) complex having a dibenzobarrelenylgroup leading to three cyclometalations†

Akihiko Ishii,*a   Yuki Yamaguchia  and  Norio Nakataa  

* Corresponding authors

a Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo 255, Sakura-ku, Saitama, Japan
E-mail: ishiiaki@chem.saitama-u.ac.jp
Fax: +81-48-858-3394

Abstract

The thermal reaction of a (dibenzobarreleneselenolato)(hydrido)platinum(II) complex gave two four-membered selenaplatinacycles, one of which is formed by hydroplatination of the Pt–H bond to the etheno bridge and the other is a vinylic C–H bond activation product, and a five-membered selenaplatinacycle formed by an aromatic C–H bond activation.

Graphical abstract: Thermal reaction of a (hydrido)(selenolato)platinum(ii) complex having a dibenzobarrelenyl group leading to three cyclometalations

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0DT00483A
Article type
Communication
Submitted
17 May 2010
Accepted
28 May 2010
First published
08 Jun 2010

Dalton Trans., 2010,39, 6181-6183

Permissions

Request permissions

Thermal reaction of a (hydrido)(selenolato)platinum(II) complex having a dibenzobarrelenyl group leading to three cyclometalations

A. Ishii, Y. Yamaguchi and N. Nakata, Dalton Trans., 2010, 39, 6181 DOI: 10.1039/C0DT00483A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements