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A palladium-catalyzed coupling reaction of 2,3-allenylic carbonates with cyclopropanols was developed, affording valuable 1,3-diene products with different functional groups efficiently under mild reaction conditions. Gram scale synthesis was easily conducted with synthetic transformations demonstrated.

Graphical abstract: A Pd-catalyzed ring opening coupling reaction of 2,3-allenylic carbonates with cyclopropanols

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