Issue 53, 2012
From the journal:

Chemical Communications

Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirality†‡

Yoko Nakano,§a   Fumiko Ichiyanagi,a   Masanobu Naito,a   Yonggang Yang*b  and  Michiya Fujiki*a  

* Corresponding authors

a Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama, Nara 630-0192, Ikoma, Japan
E-mail: fujikim@ms.naist.jp
Fax: +81 743 726049
Tel: +81 743 726040

b Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P.R. China
E-mail: ygyang@suda.edu.cn

Abstract

We observed the emergence and inversion of chiroptical handedness in three chiroptically silent dialkylpolysilanes during aggregation in limonene–methanol–THF tersolvents.

Graphical abstract: Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirality

  • This article is part of the themed collection: Chirality
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Article information

DOI
https://doi.org/10.1039/C2CC17845A
Article type
Communication
Submitted
15 Dec 2011
Accepted
09 Feb 2012
First published
10 Feb 2012

Chem. Commun., 2012,48, 6636-6638

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Chiroptical generation and inversion during the mirror-symmetry-breaking aggregation of dialkylpolysilanes due to limonene chirality

Y. Nakano, F. Ichiyanagi, M. Naito, Y. Yang and M. Fujiki, Chem. Commun., 2012, 48, 6636 DOI: 10.1039/C2CC17845A

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